Boiler passes and superheaters slag where the gas is hottest and the deposit sticks
In the radiant and first convective passes the ash is still soft enough to adhere. It builds into slag that narrows the gas path and drives flue gas temperature up through the rest of the boiler. Superheater fouling is the part that costs most, because it directly limits steam conditions and therefore export. The deposit is also where chlorine concentrates, so the same layer that costs duty is producing the conditions for high-temperature chlorine corrosion beneath it.
